Methods in Physical Chemistry

InhaltsangabeVolume 1 PART I: Gas Phase MANIPULATING THE MOTION OF COMPLEX MOLECULES: DEFLECTION, FOCUSING, AND DECELERATION OF MOLECULAR BEAMS FOR QUANTUM-STATE ANDCONFORMER SELECTION Introduction: Controlled Molecules Experimental Methods Experimental Details Selected Applications Conclusions and Perspectives LASER IONIZATION SPECTROSCOPY Introduction Basic Principles Experimental Methods Case Studies Conclusions and Perspectives Supplementary Material MASS SPECTROMETRY FOR ION CHEMISTRY AND LINKS FROM THE GAS PHASE TO 'REAL' PROCESSES Introduction Key Experimental Methods Ion Structures Ion Energetics Reactions of Neutral Molecules Studied by Mass Spectrometry Ion Catalysis Summary and Perspectives PART II: Condensed-Phase SOLID STATE NMR: A VERSATILE TOOL IN SOLID STATE CHEMISTRY AND MATERIALS SCIENCE Introduction Basic Principles Experimental Techniques Selected Applications Conclusion Supplementary Material EPR ESR EMR, AN ONGOING SUCCESS STORY Introduction Basic Principles Experimental Methods Case Studies Conclusions and Perspectives Supplementary Material BROADBAND CONDUCTIVITY SPECTROSCOPY FOR STUDYING THE DYNAMICS OF MOBILE IONS IN MATERIALS WITH DISORDERED STRUCTURES Introduction: 'Microscopy in Time' in Disordered Ionic Materials Experimental Techniques: Spanning More Than 17 Decades in Frequency Linear Response Theory: Current Density and Conductivity Conductivity Spectra: Universal Properties Detected 'First' Universality: Spectra and Modeling 'Second' Universality: Spectra and Modeling XRAY ABSORPTION SPECTROSCOPY THE METHOD AND ITS APPLICATIONS Introduction Basic Principles - the EXAFS Equation Experimental Methods Case Studies Conclusion DIFFRACTION METHODS: STRUCTURE DETERMINATION AND PHASE ANALYSIS OF SOLIDS Introduction: Diffraction - What for? Basic Principles of the Elastic Interaction of Radiation and Periodic Arrays of Atoms Methods and Their Applications Summary: Diffractometry-Where To? SMALLANGLE XRAY AND NEUTRON SCATTERING ? TWO COMPLEMENTARY METHODS TO STUDY SOFT MATTER STRUCTURE Introduction Basic Theory of Small-Angle Scattering XRays and Neutrons Selected Applications Conclusions PERTURBED GAMMA TO GAMMA ANGULAR CORRELATION Introduction Basic Principles Case Studies Conclusions and Perspectives MÖSSBAUER SPECTROSCOPY Introduction Basic Principles Experimental Methods Case Studies and Selected Applications Outlook ELECTRON ENERGY LOSS SPECTROSCOPY AS AN EXPERIMENTAL PROBE FOR THE CRYSTAL STRUCTURE AND ELECTRONIC SITUATION OF SOLIDS Introduction Basics of EELS Selected Applications of EELS Outlook Volume 2 PART III: Interfaces RAMAN SPECTROSCOPY: PRINCIPLES, BENEFITS, AND APPLICATIONS Introduction Basic Principles: Raman Scattering Experimental Methods Applications of Raman Spectroscopy Conclusion DIFFUSE REFLECTANCE INFRARED FOURIER TRANSFORM SPECTROSCOPY: AN IN SITU METHOD FOR THE STUDY OF THE NATURE AND DYNAMICS OF SURFACE INTERMEDIATES Introduction Basic Principles Experimental Set-Up Application Examples Summary PHOTOELECTRON SPECTROSCOPY IN MATERIALS SCIENCE AND PHYSICAL CHEMISTRY: ANALYSIS OF COMPOSITION, CHEMICAL BONDING, AND ELECTRONIC STRUCTURE OF SURFACES AND INTERFACES Introduction Experimental Procedure Case Studies: XPS Case Studies: UPS Conclusions and Perspectives Supplementary Material PHOTOELECTRON MICROSCOPY: IMAGING TOOLS FOR THE STUDY OF SURFACE REACTIONS WITH TEMPORAL AND SPATIAL RESOLUTION Introduction Basic Principles: Photoelectron-Based Analytical Techniques Experimental Methods Case Studies (Selected Applications) Conclusions and Perspectives Supplementary Material SECONDARY ION MASS SPECTROMETRY ? A POWERFUL TOOL FOR STUDYING ELEMENTAL DISTRIBUTIONS OVER VARIOUS LENGTH SCALES Introduction Basic Principles Experimental Methods C

InhaltsangabeVolume 1 PART I: Gas Phase MANIPULATING THE MOTION OF COMPLEX MOLECULES: DEFLECTION, FOCUSING, AND DECELERATION OF MOLECULAR BEAMS FOR QUANTUM-STATE ANDCONFORMER SELECTION Introduction: Controlled Molecules Experimental Methods Experimental Details Selected Applications Conclusions and Perspectives LASER IONIZATION SPECTROSCOPY Introduction Basic Principles Experimental Methods Case Studies Conclusions and Perspectives Supplementary Material MASS SPECTROMETRY FOR ION CHEMISTRY AND LINKS FROM THE GAS PHASE TO 'REAL' PROCESSES Introduction Key Experimental Methods Ion Structures Ion Energetics Reactions of Neutral Molecules Studied by Mass Spectrometry Ion Catalysis Summary and Perspectives PART II: Condensed-Phase SOLID STATE NMR: A VERSATILE TOOL IN SOLID STATE CHEMISTRY AND MATERIALS SCIENCE Introduction Basic Principles Experimental Techniques Selected Applications Conclusion Supplementary Material EPR ESR EMR, AN ONGOING SUCCESS STORY Introduction Basic Principles Experimental Methods Case Studies Conclusions and Perspectives Supplementary Material BROADBAND CONDUCTIVITY SPECTROSCOPY FOR STUDYING THE DYNAMICS OF MOBILE IONS IN MATERIALS WITH DISORDERED STRUCTURES Introduction: 'Microscopy in Time' in Disordered Ionic Materials Experimental Techniques: Spanning More Than 17 Decades in Frequency Linear Response Theory: Current Density and Conductivity Conductivity Spectra: Universal Properties Detected 'First' Universality: Spectra and Modeling 'Second' Universality: Spectra and Modeling XRAY ABSORPTION SPECTROSCOPY THE METHOD AND ITS APPLICATIONS Introduction Basic Principles - the EXAFS Equation Experimental Methods Case Studies Conclusion DIFFRACTION METHODS: STRUCTURE DETERMINATION AND PHASE ANALYSIS OF SOLIDS Introduction: Diffraction - What for? Basic Principles of the Elastic Interaction of Radiation and Periodic Arrays of Atoms Methods and Their Applications Summary: Diffractometry-Where To? SMALLANGLE XRAY AND NEUTRON SCATTERING TWO COMPLEMENTARY METHODS TO STUDY SOFT MATTER STRUCTURE Introduction Basic Theory of Small-Angle Scattering XRays and Neutrons Selected Applications Conclusions PERTURBED GAMMA TO GAMMA ANGULAR CORRELATION Introduction Basic Principles Case Studies Conclusions and Perspectives MÖSSBAUER SPECTROSCOPY Introduction Basic Principles Experimental Methods Case Studies and Selected Applications Outlook ELECTRON ENERGY LOSS SPECTROSCOPY AS AN EXPERIMENTAL PROBE FOR THE CRYSTAL STRUCTURE AND ELECTRONIC SITUATION OF SOLIDS Introduction Basics of EELS Selected Applications of EELS Outlook Volume 2 PART III: Interfaces RAMAN SPECTROSCOPY: PRINCIPLES, BENEFITS, AND APPLICATIONS Introduction Basic Principles: Raman Scattering Experimental Methods Applications of Raman Spectroscopy Conclusion DIFFUSE REFLECTANCE INFRARED FOURIER TRANSFORM SPECTROSCOPY: AN IN SITU METHOD FOR THE STUDY OF THE NATURE AND DYNAMICS OF SURFACE INTERMEDIATES Introduction Basic Principles Experimental Set-Up Application Examples Summary PHOTOELECTRON SPECTROSCOPY IN MATERIALS SCIENCE AND PHYSICAL CHEMISTRY: ANALYSIS OF COMPOSITION, CHEMICAL BONDING, AND ELECTRONIC STRUCTURE OF SURFACES AND INTERFACES Introduction Experimental Procedure Case Studies: XPS Case Studies: UPS Conclusions and Perspectives Supplementary Material PHOTOELECTRON MICROSCOPY: IMAGING TOOLS FOR THE STUDY OF SURFACE REACTIONS WITH TEMPORAL AND SPATIAL RESOLUTION Introduction Basic Principles: Photoelectron-Based Analytical Techniques Experimental Methods Case Studies (Selected Applications) Conclusions and Perspectives Supplementary Material SECONDARY ION MASS SPECTROMETRY - A POWERFUL TOOL FOR STUDYING ELEMENTAL DISTRIBUTIONS OVER VARIOUS LENGTH SCALES Introduction Basic Principles Experimental Methods Case Studies Conclusions and Perspectives Supplementary Material APPLICATION OF THE QUARTZ